The synthesis and characterization of substituted aminomethylglyoximes and aminophenylglyoximes and their complexes with some transition metals

Zulfikaroglu A., Taş M., Bati H., Bati B.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.33, sa.4, ss.625-638, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 4
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1081/sim-120020328
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Sayfa Sayıları: ss.625-638
  • Anahtar Kelimeler: aminomethylglyoximes, aminophenylglyoximes, vicdioxime, COPPER(II), NICKEL(II), COBALT(II), CU(II), NI(II), PALLADIUM(II), CO(II), OXIME
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

In this study, six new unsymmetrical vic-dioximes, N-(3,4-dimethylphenyl)aminomethylglyoxime ((LH2)-H-1), N-(3-chloro-4-methylphenyl)aminomethyl-glyoxime ((LH2)-H-2), N-(2,6-dimethylphenyl)aminomethyl glyoxime ((LH2)-H-3), N-(3,4-dimethylphenyl)aminophenylglyoxime ((LH2)-H-4), N-(3-chloro-4-methylphenyl)-aminophenylglyoxime ((LH2)-H-5) and N-(2,6-dimethylphenyl)aminophenylglyoxime ((LH2)-H-6) have been synthesized from chloromethylglyoxime or chlorophenylglyoxime and the corresponding substituted aromatic amines. The Co(II), Ni(II) and Cu(II) complexes of these ligands were prepared. The structures of these new ligands and their complexes are proposed based upon IR, UV-Vis, H-1 NMR spectral data, magnetic measurements, and elemental analyses.