Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide

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Yaman M., Almarhoon Z. M., ÇAKMAK Ş., Kütük H., Meral G., DEGE N.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.74, ss.41-49, 2018 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 74
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1107/s2056989017017741
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.41-49
  • Anahtar Kelimeler: crystal structure, nitrophenyl, methylacetamide, benzamide, dimethoxybenzene, Hirshfeld surface, DERIVATIVES, AMIDES
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

In the title compound, C15H14N2O5, the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)degrees. An intramolecular N-H center dot center dot center dot O hydrogen bond occurs between the imino and methoxy groups. In the crystal, weak C-H center dot center dot center dot O hydrogen bonds link the molecules into supramolecular chains propagating along the a-axis direction. pi-pi stacking is observed between parallel benzene rings of neighbouring chains, the centroid-to-centroid distance being 3.6491 (10) angstrom. Three-dimensional Hirshfeld surface analyses and two-dimensional fingerprint plots have been used to analyse the intermolecular interactions present in the crystal.