Molecular structure and EPR spectral studies of trans-Bis(perchlorato-kappa O)tetrakis(1-vinyl-1Himidazole-kappa N-3)copper(II)

Kucuk K., Celik Y., Sahin R., Karabulut B., Andaç Ö., DEGE N.

CHEMICAL PHYSICS LETTERS, cilt.592, ss.59-63, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 592
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1016/j.cplett.2013.12.007
  • Dergi Adı: CHEMICAL PHYSICS LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.59-63
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

A new copper(II) complex of 1-vinylimidazole (1-Vim) and perchlorate has been synthesized and structurally characterized. The molecular structure of the complex exhibits six coordination with a distorted octahedron geometry. The complex crystallizes in triclinic system with the space group P-1. The magnetic environment of the title complex has been identified by electron paramagnetic resonance (EPR) technique. Detailed investigations of the EPR spectra show that the local symmetry of the Cu2+ ions is rhombic. Principal values of g and hyperfine tensors were determined and the ground state wave function of Cu2+ ions was obtained using EPR parameters. (C) 2013 Elsevier B.V. All rights reserved.