The synthesis and characterization of new unsymmetrical vic-dioximes and their complexes with some transition metals

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Atıf İçin Kopyala

Batı H., Taş M., Bati B.

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.31, sa.4, ss.541-548, 2001 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 31 Sayı: 4
• Basım Tarihi: 2001
• Doi Numarası: 10.1081/sim-100104785
• Dergi Adı: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.541-548
• Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

In this study, three new unsymmetrical vic-dioimes, N-(4-methoxy-phenyl)aminomethylglyoxime (L1H2), N-(5-chloro-2-methoxyphenyl)amino-methylglyoxime (L2H2) and N-(3-chloro-4-methoxyphenyl)aminomethylglyoxime (L3H2) have been synthesized from chloromethylglyoxime and the corresponding substituted aromatic amines. Mononuclear metal complexes of these ligands have been synthesized with Co(II), Ni(II) and Cu(II) salts. The structures of these new compounds are proposed based upon elemental analyses, 1H NMR, IR spectral data and magnetic measurements.