(Carbonato-kappa O-2,O ')bis(1,10-phenanthroline-kappa N-2,N ')cobalt(III) nitrate monohydrate

Andaç, Ömer; Yolcu, Zuhal; Buyukgungor, Orhan

doi:10.1107/s1600536809052763

(Carbonato-kappa O-2,O ')bis(1,10-phenanthroline-kappa N-2,N ')cobalt(III) nitrate monohydrate

Atıf İçin Kopyala

Andaç Ö., Yolcu Z., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.66, 2010 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 66
Basım Tarihi: 2010
Doi Numarası: 10.1107/s1600536809052763
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The crystal structure of the title compound, [Co(CO3)(C12H8N2)(2)]NO3 center dot H2O, consists of Co-III complex cations, nitrate anions and uncoordinated water molecules. The Co-III cation is chelated by a carbonate anion and two phenanthroline ligands in a distorted octahedral coordination geometry. A three-dimensional supramolecular structure is formed by O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonding, C-H center dot center dot center dot pi and aromatic pi-pi stacking [centroid-centroid distance = 3.995 (1) angstrom] interactions.