3-[2-(4,4-Dimethyl-2,6-dioxocyclohexylidene)hydrazinyl]benzonitrile

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Atıf İçin Kopyala

ÇOLAK N., Aksakal D., Andaç Ö., Bueyuekguengoer O.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.66, 2010 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 66
• Basım Tarihi: 2010
• Doi Numarası: 10.1107/s1600536810013164
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
• Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The title compound, C(15)H(15)N(3)O(2), contains benzonitrile and 4,4-dimethyl-2,6-dioxocyclohexylidene groups connected via a hydrazinyl group. The structure is in the hydrazone tautomeric form in the solid state. The benzonitrile and hydrazinyl groups (3-hydrazinylbenzonitrile) are essentially coplanar with an r.m.s. deviation of 0.016 angstrom. Intramolecular N-H center dot center dot center dot O hydrogen bonding helps to stabilize the molecular structure, and weak intermolecular C-H center dot center dot center dot O hydrogen bonding is present in the crystal structure.