Development of Experimental Results by Artificial Neural Network Model for Adsorption of Cu2+ Using Single Wall Carbon Nanotubes


Geyikçi F., Çoruh S., Kılıç E.

SEPARATION SCIENCE AND TECHNOLOGY, cilt.48, sa.10, ss.1490-1499, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 48 Sayı: 10
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1080/01496395.2012.738276
  • Dergi Adı: SEPARATION SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1490-1499
  • Anahtar Kelimeler: adsorption, artificial neural network, carbon nanotubes, copper, isotherm, kinetic, HEAVY-METALS REMOVAL, AQUEOUS-SOLUTION, METHYLENE-BLUE, CONE BIOMASS, IONS, COPPER(II), BIOSORPTION, LEAD(II), SORPTION, WATER
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

Removal of copper ions from aqueous solution using single wall carbon nanotubes (SWCNTs) as a function on pH was studied using batch technique. The results indicate that adsorption is strongly dependent on pH. The adsorption of Cu2+ on SWCNTs increases slowly with increasing pH value at pH<7.0 and then the adsorption increases rapidly with increasing pH at pH>7.0. The equilibrium adsorption data were analyzed by the Langmuir, Freundlich, and Temkin adsorption isotherm models. The Freundlich adsorption model agrees well with experimental data. The pseudo-second order kinetic was the best fit kinetic model for the experimental data. The experimental results were also constructed an artificial neural network (ANN) to predict removal of copper ions. A four-layer ANN, an input layer with four neurons, two hidden layers with 13 neurons, and an output layer with one neuron (4-8-5-1) is constructed. Different training algorithms are tested on the model proposed to obtain the best weights and bias values for ANN. Our results suggest that SWCNTs have a good potential application in environmental protection. This novel modeling tool is newly grown and has been used yet to model the above-mentioned experiments for SWCNTs.