Solvent effects on the solvolyses of N-benzoyl-arenesulfonimidoyl chlorides

Kutuk H., Tillett J. G.

Phosphorus, Sulfur and Silicon and Related Elements, cilt.175, ss.35-47, 2001 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 175
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1080/10426500108040254
  • Dergi Adı: Phosphorus, Sulfur and Silicon and Related Elements
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.35-47
  • Anahtar Kelimeler: Solvent effects, Solvolysis, Sulfonimidoyl chlorides
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

Rates of solvolyses of N-benzoyl-arenesulfonimidoyl chlorides have been studied in different compositions of aqueous organic solvents and analysed in terms of the mol fraction of organic solvent, the dielectric constant, the Kirkwood function, the polarisibility, some ENT values, a multiparameter equation and the Grunwald-Winstein equation. All these criteria were consistent with a concerted bimolecular SN2 mechanism of solvolysis.