Crystal structure and Hirshfeld surface analysis of (succinato-kappa O)[N,N,N ',N '-tetrakis(2-hydroxyethyl)ethylenediamine-kappa(5) O,N,N ',O ',O '']nickei(II) tetrahydrate

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Kansiz S., DEGE N., Topcu Y., ATALAY Y., Gaidai S.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.74, ss.1700-1710, 2018 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 74
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1107/s2056989018015359
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.1700-1710
  • Anahtar Kelimeler: crystal structure, nickel(II) complex, succinic acid, Hirshfeld surface, COMPLEXES, NICKEL(II), ACID
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

In the title compound, [Ni(C10H24N2O4)(C4H4O4)]center dot 4H(2)O, the Ni-II cation is octahedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine molecule. In the crystal, molecules are linked by O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional supramolecular architecture. Hirshfeld surface analyses and two-dimensional fingerprint plots were used to analyse the intermolecular interactions present in the crystal, indicating that the most important contributions for the crystal packing are from H center dot center dot center dot H (63.3%) and H center dot center dot center dot O/O center dot center dot center dot H (34.5%) interactions.