trans-Bis(ethylenediamine-kappa N-2,N ')bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2 lambda(6),3-oxathiazin-3-ido-kappa N)copper(II)

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Atıf İçin Kopyala

DEGE N., Demirtas G., İçbudak H.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.68, 2012 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 68
• Basım Tarihi: 2012
• Doi Numarası: 10.1107/s1600536811051658
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

In the crystal structure of the title compound, [Cu(C4H4NO4S)(2)(C2H8N2)(2)], the Cu2+ ion resides on a centre of symmetry. The environment of Cu2+ ion is a distorted octahedron. The axial bond lengths between the Cu-II ion and the N atoms are considerably longer than the equatorial bond distances between the Cu-II ion and the N atoms of the ethylenediamine ligand as a consequence of the Jahn-Teller effect. The molecular conformation is stabilized by intramolecular N-H center dot center dot center dot O hydrogen bonds. In the crystal, molecules are connected by intermolecular N-H center dot center dot center dot O hydrogen bonds into chains running along the a axis.