Synthesis, thermal, spectroscopic and structural properties of di(aqua)bis(N,N'-dimethylethylenediamine-k(2)N,N')copper(II) acesulfamate

Icbudak H., Uyanik A., Bulut A., Arici C., Uelkue D.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, cilt.222, sa.8, ss.432-436, 2007 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 222 Sayı: 8
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1524/zkri.2007.222.8.432
  • Dergi Adı: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.432-436
  • Anahtar Kelimeler: acesulfamate, N,N'-dimethylethylenediamine, mass spectrometry, thermal analysis, single crystal structure analysis, X-ray diffraction, NICKEL(II) COMPLEXES, CRYSTAL-STRUCTURES, SOLID-STATE, COPPER(II), N,N-DIETHYLETHYLENEDIAMINE, THERMOCHROMISM, CO(II), NI(II), LIGAND
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The complex [Cu(C4H12N2)(2)(H2O)(2)](2+) [(C4H4NO4S)(-)](2), which is the first structurally characterized complex with acesulfamate as the counter anion, has been synthesized and characterized by elemental analyses, magnetic and conductivity measurements, UV/vis, FT-IR and mass spectra. The thermal behaviour of the complexes was studied by simultaneous TG, DTG and DTA methods in a static air atmosphere. In the crystal structure, the copper cation, lying on a crystallographic centre of symmetry, adopts an elongated octahedral trans-[CuN4O2] coordination geometry, with long axial Cu-O(aqua) bond length and short equatorial Cu-N bonds, of 2.479(2), 2.035(2) and 2.051(2) angstrom, respectively. The coordinated water molecules together with the amine part of the dimethylethylene-diamine molecule link the acesulfamate ions to the metal complex via intermolecular hydrogen bonds.