[1,3-bis(2-ethoxyphenyl)imidazolidin-2-ylidene]bromo(cycloocta-1,5-diene)rhodium(I)

Dincer, M; Özdemir, Namık; Gunay, ME; Cetinkaya, B; Buyukgungor, O

doi:10.1107/s0108270105013284

[1,3-bis(2-ethoxyphenyl)imidazolidin-2-ylidene]bromo(cycloocta-1,5-diene)rhodium(I)

Atıf İçin Kopyala

Dincer M., Özdemir N., Gunay M., Cetinkaya B., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, cilt.61, 2005 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 61
Basım Tarihi: 2005
Doi Numarası: 10.1107/s0108270105013284
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Ondokuz Mayıs Üniversitesi Adresli: Hayır

Özet

The title complex, [RhBr(C8H12)(C19H22N2O2)], has a distorted square-planar geometry. There are two molecules, A and B, in the asymmetric unit. The Rh-C bond distance between the N-heterocyclic ligand and the metal atom is 2.039 (2) angstrom in molecule A and 2.042 (2) angstrom in molecule B. The angle between the carbene heterocycle and the coordination plane is 87.56 (12)degrees in molecule A and 87.03 (11)degrees in molecule B. It is shown that the average Rh-C(COD) (COD is cyclooctadiene) distance is linearly dependent on the Rh-(imidazolidine)distance in this type of compound. This can be ascribed to the steric hindrance produced by the packing. The crystal structure contains intramolecular C-H center dot center dot center dot O and intermolecular C-H center dot center dot center dot Br interactions.