Synthesis, characterization and spectral studies of triethanolamine complexes of metal saccharinates. Crystal structures of [Co(TEA)2](SAC)2 and [Cu2(μ-TEA)2(SAC)2]·2 (CH3OH)

Topcu Y., Andaç Ö., YILMAZ V. T., Harrison W.

Journal of Coordination Chemistry, cilt.55, sa.7, ss.805-815, 2002 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 55 Sayı: 7
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1080/0095897022000001557
  • Dergi Adı: Journal of Coordination Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.805-815
  • Anahtar Kelimeler: Crystal structures, Saccharin complexes, Triethanolamine complexes
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The novel transition metal saccharinate complexes of triethanolamine (TEA) have been synthesized and characterized by elemental analyses, magnetic moments, UV-Vis and IR spectra. Mn(II), Co(II), Ni(II), Zn(II), Cd(II) and Hg(II) forro mononuclear complexes of [M(TEA)2](SAC)2, where SAC is the saccharinate ion, while the Cu(II) complex is dimeric. The TEA ligand acts asa tridentate N,O,O′-donor ligand and one ethanol group is not involved in coordination. The SAC ion does not coordinate to the metal ions and is present as the counter-ion in the Mn(II), Co(II), Ni(II), Zn(II), Cd(II) and Hg(II) complexes, but coordinates to the Cu(II) ion asa monodentate ligand. The crystal structures of the [Co(TEA)2](SAC)2 and [Cu2(μ-TEA)2(SAC)2]·2 (CH3OH) complexes were determined by single crystal x-ray diffraction. The Co(II) ion has a distorted octahedral coordination by two TEA ligands. The Cu(II) complex crystallizes as a dimethanol solvate and has doubly alkoxo-bridged centrosymmetric dimeric molecules involving two tridentate triethanolaminate (deprotonated TEA) and two monodentate SAC ligands. The geometry of each Cu(II) ion is a distorted square pyramid. Both crystal structures are stabilized by hydrogen bonds to form a three-dimensional network.