The Tetra[N-phenylanthranilato](O,O')bis[(2-amino-4-methyl)pyridine Copper(II)] Complex Crystal

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Atıf İçin Kopyala

Taş M., Titiz A., Karabag E., Kaya M., Ataseven M., DAL H.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.43, sa.9, ss.1212-1223, 2013 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 43 Sayı: 9
• Basım Tarihi: 2013
• Doi Numarası: 10.1080/15533174.2012.757237
• Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.1212-1223
• Ondokuz Mayıs Üniversitesi Adresli: Hayır

Özet

Tetra[N-phenylanthranilato](O,O)bis[2-amino-4-methyl) pyridine copper(II)] (bisdichloromethane solvate and unsolvate) in one crystalline contains two independent binuclears, one of which is unsolvate and the other one is dichloromethane solvate. The phenyl ring planes in the asymmetric units were not parallel to each other [44.47(14)degrees and 52.50(13)degrees for unsolvate unit, 53.30(14)degrees and 49.59(13)degrees for solvate unit] and the distance between the two centers of phenyl rings was measured as 5.064 angstrom (for Cg2-Cg3), 5.005 angstrom (for Cg4-Cg5), 5.048 angstrom (for Cg7-Cg8), and 5.088 angstrom (for Cg9-Cg10) for NPA ligands. The complex molecules showed three dimensional supramolecular networks by OH center dot center dot center dot O, CH center dot center dot center dot O, CH center dot center dot center dot, and center dot center dot center dot interactions.