Atıf İçin Kopyala
Guemuesada R., Guenay M. E., Özdemir N., Cetinkaya B.
JOURNAL OF COORDINATION CHEMISTRY, cilt.69, sa.9, ss.1463-1472, 2016 (SCI-Expanded)
-
Yayın Türü:
Makale / Tam Makale
-
Cilt numarası:
69
Sayı:
9
-
Basım Tarihi:
2016
-
Doi Numarası:
10.1080/00958972.2016.1185780
-
Dergi Adı:
JOURNAL OF COORDINATION CHEMISTRY
-
Derginin Tarandığı İndeksler:
Science Citation Index Expanded (SCI-EXPANDED), Scopus
-
Sayfa Sayıları:
ss.1463-1472
-
Anahtar Kelimeler:
Chiral bicyclic N-heterocyclic carbene, expanded ring N-heterocyclic carbene, PEPPSI-type palladium complex, camphoric acid, X-ray diffraction, RHODIUM COMPLEXES, CATALYSTS
-
Ondokuz Mayıs Üniversitesi Adresli:
Evet
Özet
Eight bicyclic amidinium precursors (3), prepared from R,S-tmcp (R,S-tmcp: (1R,3S)-diamino-1,2,2-trimethylcyclopentane) were described. Only five of the precursors (3a-e) could be converted to palladium complexes, (PdX2(6,7-NHC)PEPPSI) (4) by treatment with PdCl2, K2CO3, and pyridine (additional KBr was used for (PdBr2(6,7-NHC)PEPPSI)). The salts and complexes were fully characterized by spectroscopic methods and X-ray crystallography.