A mixed ligand copper(II) complex with 5,5-dimethylhydantoin and t-butylamine

Taş M., Soylu M. S., Buyukgungor O.

POLISH JOURNAL OF CHEMISTRY, cilt.82, sa.5, ss.973-980, 2008 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 82 Sayı: 5
  • Basım Tarihi: 2008
  • Dergi Adı: POLISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.973-980
  • Anahtar Kelimeler: hydantoins, 5,5-dimethylhydantoin, t-butylamine, copper(II) complex, COORDINATION GEOMETRY, CRYSTAL-STRUCTURES
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The structure of the newly synthesized complex, trans-bis(t-butylamine)-bis(5,5-dimethylhydantoinato)copper(II) dihydrate was determined by single crystal X-ray crystallography. Thermal analyses, FT-IR spectra and magnetic susceptibility were also studied. The complex crystallizes in the orthorhombic system, space group Pbca. The complex has a slightly distorted square planar [CuN4] coordination with 5,5-dimethylhydantoinato and t-butylamine ligands bonded to the copper(II) ion via their deprotonated N(3) and amine nitrogen atoms, respectively. The Cu-N-hyd, and Cu-N-amine bond lengths are 1.983 and 2.019 angstrom.