Synthesis and crystal structure of square-planar and mixed ligand octahedral nickel(II) O,O′-dicyclopentyl dithiophosphate complexes

Taş, Murat; Yaǧan, Mehtap; Bati, Hümeyra; Bati, Bekir; Büyükgüngör, Orhan

Synthesis and crystal structure of square-planar and mixed ligand octahedral nickel(II) O,O′-dicyclopentyl dithiophosphate complexes

Taş M., Yaǧan M., Bati H., Bati B., Büyükgüngör O.

Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, cilt.47, sa.1, ss.37-42, 2008 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 47 Sayı: 1
Basım Tarihi: 2008
Dergi Adı: Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.37-42
Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

Ammonium O,O′-dicyclopentylphosphorodithioate (dcpdtp) has been synthesized from phosphorus pentasulphide and cyclopentanol in the presence of ammonia gas. Its complexes, I=[Ni(dcpdtp)2] and II=[Ni(bp) 2(dcpdtp)2] (bp=4-benzylpiperidine), have been synthesized and their structures characterized by using UV-vis, IR spectroscopy, magnetic susceptibility measurements and X-ray single crystal structural analysis. The complexes crystallize in the triclinic system (space groups P 1̄) and exhibit a slightly distorted square planar [NiS4] and trans-octahedral [NiS4N2] geometry for the complexes I and II, respectively.