2-{(E)-[(3-Iodo-4-methylphenyl) imino]methyl}-4-(trifluoromethoxy) phenol


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Pekdemir M., Isik S., Alaman Ağar A.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.68, 2012 (ESCI) identifier identifier identifier

Özet

The title compound, C15H11F3INO2, adopts the enol-imine tautomeric form. The molecule displays an E conformation with respect to the imine C=N double bond. The dihedral angle between the two benzene rings is 12.4 (2)degrees. The molecular conformation is stabilized by an intramolecular O-H center dot center dot center dot N hydrogen bond, which generates an S(6) ring motif. The trifluoromethoxyphenyl group is disordered over two sites with an occupancy ratio of 0.621 (6): 0.379 (6). The crystal structure features C-H center dot center dot center dot center dot interactions.