Synthesis, spectral characterisation and thermal behaviours of some new p-tert-butylcalix[4]arene and calix[4]arene-esters containing acryloyl groups

ÖZKINALI S., Kocaokutgen H.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1031, ss.70-78, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1031
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1016/j.molstruc.2012.06.061
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.70-78
  • Anahtar Kelimeler: Acryloyl esters of calixarene, Spectral analysis, Thermal analysis, CALIXARENES, DERIVATIVES, COMPLEXATION
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The mono-, di-, tri-, and tetra-acryloyl esters of p-tert-butylcalix[4]arene and calix[4]arene were synthesised by reacting acryloyl chloride with sodium salts of p-tert-butylcalix[4]arene and calix[4]arene in THF. The structures of these compounds were characterised by IR, UV-VIS, H-1 NMR, and C-13 NMR. Thermal behaviour of the compounds were also examined by means of differential thermal analysis (DTA), thermogravimetry (TG), and derivative thermogravimetry (DTG). (C) 2012 Elsevier B.V. All rights reserved.