1-{(Z)-[2-Methoxy-5-(trifluoromethyl)anilino]methylidene}naphthalen-2(1H)one


Creative Commons License

Kargili H., Alaman Ağar A., Alpaslan G., Bueyuekguengoera O., Erdoenmez A.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.69, 2013 (ESCI) identifier identifier identifier

Özet

The title compound, C19H14F3NO2, crystallizes in the ketoamine tautomeric form, with a strong intramolecular NH center dot center dot center dot O hydrogen bond. The molecule is almost planar; the dihedral angle between the naphthalene ring system and the benzene ring is 4.60 (7)degrees. In the crystal, molecules are linked into chains along the c axis by C-H center dot center dot center dot O hydrogen bonds. The F atoms of the trifluoromethyl group are disordered over two positions with refined site occupancies of 0.668 (9) and 0.332 (9).