Diacetatobis(2-aminobenzothiazole-kappa N)cobalt(II)

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Atıf İçin Kopyala

Bati H., Saracoglu H., Caliskan N., Soylu S.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, cilt.61, 2005 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 61
• Basım Tarihi: 2005
• Doi Numarası: 10.1107/s0108270105016811
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The title complex, [Co(C2H3O2)(2)(C7H6N2S)(2)], contains a Co centre with a slightly distorted tetrahedral coordination geometry, involving two acetate ligands and two N atoms from the thiazole moiety [ Co - O = 2.0025 ( 14) and 1.9953 ( 16) angstrom, and Co - N = 2.0524 ( 18) and 2.0568 ( 18) angstrom]. The interplanar angle between the two benzothiazole moieties is 77.86 ( 3) degrees. The amine groups, acting as donors, participate in intra- and intermolecular N - H center dot center dot center dot O hydrogen bonds, with N center dot center dot center dot O distances in the range 2.806 ( 2) - 2.857 ( 2) angstrom.