Synthesis, Molecular Structure and Spectroscopic Studies of 6,6'-(1E,1'E)-(Ethane-1,2-Diylbis(azan-1-yl-1-ylidene))bis(Phenylmethan-1-yl-1-ylidene)bis(3-(Octyloxy)phenol)

TANAK H., Meral S., Alaman Ağar A.

CRYSTALLOGRAPHY REPORTS, cilt.65, sa.7, ss.1217-1220, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 65 Sayı: 7
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1134/s1063774520070251
  • Dergi Adı: CRYSTALLOGRAPHY REPORTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Compendex, INSPEC, zbMATH
  • Sayfa Sayıları: ss.1217-1220
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

6,6'-(1E,1'E)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(phenylmethan-1-yl-1-ylidene)bis(3-(octyloxy)phenol) has been synthesized and characterized by FTIR, H-1, C-13 NMR and single-crystal X-ray determination. The compound crystallizes in monoclinic space group C2/c with Z = 4 in the unit cell. The asymmetric unit of the compound contains one half-organic molecule. The molecule is located about a two-fold rotation axis which bisects the central C14-C14(i) bond. The dihedral angle between the phenyl rings is 68.46(11)degrees. In the crystal, intramolecular O-H...N hydrogen bonds generates a six-membered ring, producing an S(6) ring motif. The crystal packing is also stabilized by C-H...pi interactions.