Crystal structure of (E)-3-fluoro-N-((5-nitrothiophen-2-yl)methylene)aniline

Karatas A., TANAK H., Alaman Ağar A.

CRYSTALLOGRAPHY REPORTS, cilt.61, sa.3, ss.410-413, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 61 Sayı: 3
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1134/s1063774516030147
  • Dergi Adı: CRYSTALLOGRAPHY REPORTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.410-413
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The structure of the title compound C11H7FN2O2S was characterized by single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P2(1)/n with Z = 12, i.e. with three molecules in asymmetric unit. The molecules are not planar: the dihedral angles between the planes of thiophene and the benzene rings are 42.3(3)A degrees, 42.0(3)A degrees, and 48.9(2)A degrees. In the crystal, intermolecular C-H center dot center dot center dot F interactions link the molecules through R (2) (2) (14) ring motif. The crystal packing is also stabilized by pi center dot center dot center dot pi interactions.